Autoruns shows programs that run during system bootup or login, as well as entries in the order Windows processes them. These programs include ones in your startup folder, Run, RunOnce and other Registry keys. You can configure Autoruns to show other locations, including Explorer shell extensions, toolbars, browser helper objects, Winlogon notifications, auto-start services and much more. Autoruns goes way beyond the MSConfig utility.
A 64-bit version is available (within the folder).
Alternatively, Autoruns Portable is stealth and will only show the EULA once.